含吡咯并吡咯二酮单元卟啉共聚物、其制备方法和应用

Abstract

本发明涉及有机材料技术领域,提供一种含吡咯并吡咯二酮单元卟啉共聚物,其为结构式(I)表示的共聚物,式中,R1、R2、R3、R4、R5、R6为相同或不相同的C1-C32的烷基;n为1-100的整数。本发明还提供该含吡咯并吡咯二酮单元卟啉共聚物的制备方法和应用。上述含吡咯并吡咯二酮单元卟啉共聚物由于具有芴基卟啉结构和吡咯并吡咯二酮单元,具有优异的光热稳定性和成膜性,且该聚合物中引入吡咯并吡咯二酮和卟啉基团,加宽了聚合物的光谱响应范围。
The invention relates to the technical field of organic materials, and provides pyrrole-pyrrole-dione unit-containing porphyrin copolymer. The copolymer is shown by a structural formula (I), wherein R1, R2, R3, R4, R5 and R6 are the same or different C1-C32 alkyl groups; and n is an integer of 1-100. The invention also provides a preparation method and application of the pyrrole-pyrrole-dione unit-containing porphyrin copolymer. Since the pyrrole-pyrrole-dione unit-containing porphyrin copolymer has a fluorenyl porphyrin structure and a pyrrole-pyrrole-dione unit, so that the copolymer has superior light and heat stability and filming property; and pyrrole-pyrrole-dione and porphyrin groups are introduced into the polymer, so that the spectral response range of the polymer is widened.

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    CN-1724534-AJanuary 25, 2006复旦大学含芴二芳基乙烯金属氮杂卟啉化合物及其制备方法和应用

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